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Selective transport of copper(II) ions across polymer inclusion membrane with aromatic β–diketones as carriers
Elżbieta Radzymińska-Lenarcik 1
,
 
Katarzyna Witt 2
,
 
Daria Bożejewicz 2
 
 
 
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1
Faculty of Chemical Technology and Engineering, University of Technology and Life Sciences in Bydgoszcz,
 
2
Faculty of Chemical Technology and Engineering, UTP University of Sciences and Technology, Seminaryjna 3, PL-85326 Bydgoszcz, Poland
 
 
Corresponding author
Elżbieta Radzymińska-Lenarcik   

Faculty of Chemical Technology and Engineering, University of Technology and Life Sciences in Bydgoszcz,, Seminaryjna 3, 85-326 Bydgoszcz, Poland
 
 
Physicochem. Probl. Miner. Process. 2018;54(3):741-750
DOI: https://doi.org/10.5277/ppmp1868
 
 
Article (PDF)
References (45)
 
KEYWORDS
polymer inclusion membrane
copper(II)
cobalt(II)
nickel(II)
metal ion separation
β-diketones
 
TOPICS
Environmental aspects of mineral processing
 
ABSTRACT
The transport of Cu(II) ions from an equimolar mixture of Co(II), Ni(II), and Cu(II) ions as well as from solutions containing only Cu(II) ions in the feed phase through polymer inclusion membranes (PIMs) with aromatic β–diketones as carriers has been investigated. The polymer membranes consisted of polyvinylchloride (PVC) as the support, bis(2-ethylhexyl)adipate (ADO) as plasticizer, and aromatic β–diketones (benzoylacetone (1) and dibenzoylmethane (2)) as ion carriers. The transport selectivity of PIMs with 1 and 2 was: Cu(II) > Co(II) > Ni(II). The highest recovery factors of Cu(II) ions were observed for 1 (94.0%), whereas for Co(II) and Ni(II) the factors were 21.4 and 7.3%, respectively. The Cu(II)/Co(II) and Cu(II)/Ni(II) selectivity coefficients were equal to 8.9 and 33.7 (for 1), 6.4 and 28.3 (for 2), respectively.
 
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