Kinetic research of quinoline, pyridine and phenol adsorption on modified coking coal
,
 
,
 
,
 
,
 
,
 
,
 
 
 
 
More details
Hide details
1
School of Chemical Engineering and Technology, China University of Mining & Technology
 
2
National Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences
 
 
Corresponding author
Hongxiang Xu   

China university of mining and technology(Beijing), xueyuan road Ding No.11, 100083 Beijing, China
 
 
Physicochem. Probl. Miner. Process. 2018;54(3):965-974
 
KEYWORDS
TOPICS
ABSTRACT
Adsorption is widely used in wastewater treatment. In this work, the removal of quinoline, pyridine and phenol from coking wastewater by using modified coking coal, which was treated by four different modification methods i.e. acidification sodium hydroxide (5 mol/dm3), hydrochloric acid (5 mol/dm3) and acetic acid (5 mol/dm3) and low-temperature (105 oC) oxidation, was investigated. The modified coal was characterized by the surface area analysis, SEM, total acidity and basicity and FT-IR. The results showed that the surface area from high to low follows the order: modification with acetic acid, modification with hydrochloric acid, raw coal, modification with sodium hydroxide and modification with low-temperature. Experimental data were fitted to pseudo-first-order, pseudo-second-order and intra-particle diffusion. The adsorption of all followed pseudo-second-order kinetics. The result showed that the removal efficiency of coal modified by hydrochloric acid and acetic acid are higher than raw coal, while modified by sodium hydroxide and low-temperature are lower than raw coal., The coal modified by hydroxide acid had the best adsorption capacity.
REFERENCES (27)
1.
AKSU, Z. & J. YENER, 2001. A comparative adsorption/biosorption study of mono-chlorinated phenols onto various sorbents. Waste Manage (Oxford), 21, 695-702.
 
2.
ANDERSSON, K. I., M. ERIKSSON & M. NORGREN, 2011. Removal of Lignin from Wastewater Generated by Mechanical Pulping Using Activated Charcoal and Fly Ash: Adsorption Kinetics. Ind Eng Chem Res, 50, 7733-7739.
 
3.
BADMUS, M. A. O. & T. O. K. AUDU, 2009. Periwinkle shell: Based granular activated carbon for treatment of chemical oxygen demand (COD) in industrial wastewater. Can J Chem Eng, 87, 69–77.
 
4.
CA, B., 2006. Applicability of the various adsorption models of three dyes adsorption onto activated carbon prepared waste apricot. J Hazard Mater, 135, 232-241.
 
5.
CAI, C. F. & C. G. TANG, 2012. Competitive adsorption of main organic pollutants from coking wastewater on coking coal., Journal of China Coal Society, 37, 1753-1759.
 
6.
CAI, C. F., X. Q. ZHENG, G. HUI & M. J. ZUO, 2010. Adsorption kinetics of organic in coking wastewater effluent from secondary sedimentation tank on coal., Journal of China Coal Society, 35, 299-302.
 
7.
CARVAJAL-BERNAL, A. M., F. G MEZ, L. GIRALDO & J. C. MORENO-PIRAJ N, 2015. Adsorption of phenol and 2,4-dinitrophenol on activated carbons with surface modifications. Microporous & Mesoporous Materials, 209, 150-156.
 
8.
FAN, G., J. LIU, Y. CAO, L. FENG & H. XU, 2016. Adsorption mechanism of sodium oleate on titanium dioxide coated sensor surface using quartz crystal microbalance with dissipation. Physicochemical Problems of Mineral Processing, 52, 597-608.
 
9.
FLETCHER, A. J., A. YAPRAK UYGUR & K. M. THOMAS, 2007. Role of Surface Functional Groups in the Adsorption Kinetics of Water Vapor on Microporous Activated Carbons. Journal of Physical Chemistry C, 111, 8349-8359.
 
10.
GAO, L., S. LI & Y. WANG, 2016. Effect of different pH coking wastewater on adsorption of coking coal., Water Science & Technology 73, 582.
 
11.
GERENTE, C., V. K. C. LEE, P. L. CLOIREC & G. MCKAY, 2007. Application of Chitosan for the Removal of Metals From Wastewaters by Adsorption—Mechanisms and Models Review. Critical Reviews in Environmental Science & Technology, 37, 41-127.
 
12.
GUO, Y. & R. M. BUSTIN, 1998. FTIR spectroscopy and reflectance of modern charcoals and fungal decayed woods: implications for studies of inertinite in coals. International Journal of Coal Geology, 37, 29-53.
 
13.
H.P, W. S. A. T., D. E, H. W & S. R, 1964. Surface Oxides of Carbon. Angew Chem Int Ed, 3, 669-677.
 
14.
KAYA, E. M. Ö., A. S. ÖZCAN, Ö. G K & A. ÖZCAN, 2013. Adsorption kinetics and isotherm parameters of naphthalene onto natural- and chemically modified bentonite from aqueous solutions. Adsorption-journal of the International Adsorption Society, 19, 879-888.
 
15.
KIM, Y. M., D. PARK, D. S. LEE & J. M. PARK, 2007. Instability of biological nitrogen removal in a cokes wastewater treatment facility during summer. J Hazard Mater, 141, 27-32.
 
16.
LEDESMA, E. B., P. F. NELSON & J. C. MACKIE, 1998. The formation of nitrogen species and oxygenated PAH during the combustion of coal volatiles. Symposium on Combustion, 27, 1687-1693.
 
17.
MOHAN, S. V. & J. KARTHIKEYAN, 1997. Removal of lignin and tannin colour from aqueous solution by adsorption onto activated charcoal., Environ Pollut, 97, 183.
 
18.
POLAT, H., M. MOLVA & M. POLAT, 2006. Capacity and mechanism of phenol adsorption on lignite. Int J Miner Process, 79, 264-273.
 
19.
SARKAR, M., A. R. SARKAR & J. L. GOSWAMI, 2007. Mathematical modeling for the evaluation of zinc removal efficiency on clay sorbent. J Hazard Mater, 149, 666.
 
20.
SRIVASTAVA, V. C., I. D. MALL & I. M. MISHRA, 2005. Treatment of pulp and paper mill wastewaters with poly aluminium chloride and bagasse fly ash. Colloids & Surfaces A Physicochemical & Engineering Aspects, 260, 17-28.
 
21.
WANG, M. J., C. H. FU, L. P. CHANG & K. C. XIE, 2012. Effect of fractional step acid treatment process on the structure and pyrolysis characteristics of Ximeng brown coal., Journal of Fuel Chemistry & Technology, 40, 906-911.
 
22.
WANG, X. H., L. FENG, X. C. LIU, Y. ZHANG & M. ZHANG, 2000. Effect of NaOH treatment on Water Sorption of Lignite. Research & Exploration in Laboratory, 33, 19-20.
 
23.
WU, J. & H. Q. YU, 2006. Biosorption of 2,4-dichlorophenol from aqueous solution by Phanerochaete chrysosporium biomass: isotherms, kinetics and thermodynamics. J Hazard Mater, 137, 498-508.
 
24.
XIA, C. B., HE, XIANGZHU, 2000. Adsorption heavy metal ion for sulfonated lignite. Material Protection, 33, 19-20.
 
25.
ZHANG, X., Z. HAO, S. ZHANG & Y. YANG, 2017. Difference of nano-scale pore changes and its control mechanism for tectonic coal under solvent reconstruction. Journal of China University of Mining & Technology, 46, 148-154.
 
26.
ZHAO, W. T., X. HUANG & D. J. LEE, 2009. Enhanced treatment of coke plant wastewater using an anaerobic–anoxic–oxic membrane bioreactor system. Separation & Purification Technology, 66, 279-286.
 
27.
ZHU, H., LI, HU LIN , OU, ZHESHEN , WANG, DIANZUO, XIAOLI LV, 2001. Study on Surface Modification of Different Rank Coals by Using FTIR. Journal of China University of Mining &Technology, 30, 366-370.
 
eISSN:2084-4735
ISSN:1643-1049
Journals System - logo
Scroll to top