Evaluation of sodium petroleum sulfonates with different molecular weights for flotation of kyanite ore
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School of Resources and Environmental Engineering, Wuhan University of Technology
 
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Wuhan University of Technology
 
 
Publication date: 2017-04-30
 
 
Corresponding author
Huimin Gao   

Wuhan University of Technology, No.122 Luoshi Road, Hongshan District, 430070 Wuhan, China
 
 
Physicochem. Probl. Miner. Process. 2017;53(2):956-968
 
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ABSTRACT
The flotation performance of sodium petroleum sulfonates with different molecular weights was evaluated for flotation of a kyanite ore, by investigating valuable mineral recovery-grade, flotation kinetics and gangue entrainment. The results indicated that the higher molecular weight of agent, the higher final cumulative kyanite recovery was, with the maximum value of 72% being obtained with KY-3 with the molecular weight of 438. The final cumulative kyanite grade initially increased, and then decreased with the molecular weight increasing. In other words, the maximum final cumulative kyanite grade (i.e. 89.05%) was obtained with KY-2 with the molecular weight of 392. The kyanite flotation kinetics followed the first order kinetics well, while the modified flotation rate constant showed a decreasing trend after the initial increase as the molecular weight increased. In addition, the overall entrainment degree decreased with decreasing molecular weight of sodium petroleum sulfonates. The use of KY-2 in kyanite flotation was an attractive option in comparison with KY-1 and KY-3.
 
REFERENCES (52)
1.
ADKINS, S. J., PEARSE, M. J., 1992, The influences of collector chemistry on kinetics and selectivity in base-metal sulphide flotation. Minerals Engineering, 5(3), 295- 310.
 
2.
AGAR, G. E., BARRETT, J. J., 1983, The use of flotation rate data to evaluate reagents. CIM bulletin, 76(851), 157- 162.
 
3.
AMANULLAH, S., RAO, G. M., SATYANARAYANA, K., 1990, Beneficiation of mica-quartz-bearing kyanite. InInd. Miner. (Suppl.) Processing Developments. 9th Industrial Minerals International Congress, Sydney, 271, 24- 29.
 
4.
ASGHAR, A., AHMAD, H., BEHNAM, F., 2015, Investigating the first-order flotation kinetics models for Sarcheshmeh copper sulfide ore. International Journal of Mining Science and Technology, 25(5), 849- 854.
 
5.
BHATTACHARYA, S., DEY, S., 2008, Evaluation of frother performance in coal flotation: A critical review of existing methodologies. Mineral Processing & Extractive Metallurgy Review, 29(4), 275- 298.
 
6.
BULUT, G., YURTSEVER, C., 2004, Flotation behaviour of Bitlis kyanite ore. International Journal of Mineral Processing, 73(1), 29- 36.
 
7.
DING H., 1991, Study of flotation kinetic models of graphite in jinxi, Jiangxi Province. Multipurpose Utilization of Mineral Resources, (2), 43- 47. (in Chinese).
 
8.
GONG J., PENG Y., Bouajila, A., Ourriban, M., YEUNG, A., LIU, Q., 2010, Reducing quartz gangue entrainment in sulphide ore flotation by high molecular weight polyethylene oxide. International Journal of Mineral Processing, 97(1), 44- 51.
 
9.
GÜLER, T., AKDEMIR, Ü., 2012, Statistical evaluation of flotation and entrainment behavior of an artificial ore. Transactions of Nonferrous Metals Society of China, 22(1), 199- 205.
 
10.
GUO H.S., YE F.B., LI W.F., SONG X.Z., XIE G.F., 2015, Preparation and characterization of foamed microporous mullite ceramics based on kyanite. Ceramics International, 41(10), 14645- 14651.
 
11.
HOSTEN, C., TEZCAN, A., 1990, The influence of frother type on the flotation kinetics of a massive copper sulphide ore. Minerals Engineering,3(6), 637- 640.
 
12.
HOU Z.S., LI Z.P., WANG H.Q., 2000, The interaction of sodium dodecyl sulfonate and petroleum sulfonate with nonionic surfactants (Triton X-100, Triton X-114).Colloids and Surfaces A: Physicochemical and Engineering Aspects, 166(1), 243- 249.
 
13.
JAMERSON, H., DIXON, G. B., BROWN, J. J., 2001, Mineralogy of the kyanite beneficiation process.InUNITECR'01. Proc. Unified Int. Tech. Conf. on Refractories. 7th Biennial Worldwide Congress, (2), 711- 726.
 
14.
JOWETT, A., GHOSH, S. K., 1964, Flotation kinetics: investigations leading to process optimization.In7th Int. Miner. Process. Congr. (Vol. 1, pp. 175- 184). Gordon and Breach New York.
 
15.
KIRJAVAINEN, V. M., 1996, Review and analysis of factors controlling the mechanical flotation of gangue minerals. International journal of mineral processing, 46(1), 21- 34.
 
16.
KOWALCZUK P.B., ZAWALA J., KOSIOR D., DRZYMALA J., MALYSA K., 2016, Three-phase contact formation and flotation of highly hydrophobic polytetrafluoroethylene in the presence of increased dose of frothers. Industrial & Engineering Chemistry Research 55(3), 839–843.
 
17.
KRACHT W, OROZCO Y, ACUÑA C., 2016, Effect of surfactant type on the entrainment factor and selectivity of flotation at laboratory scale. Minerals Engineering, 92, 216- 220.
 
18.
KUSTOV, A. D., PARFENOV, O. G., SOLOVYOV, L. A., VERESHCHAGIN, S. N., 2014, Kyanite ore processing by carbochlorination. International Journal of Mineral Processing, 126, 70- 75.
 
19.
LI H.Q., FENG Q.M., YANG S.Y., OU L.M., LU Y.,2014, The entrainment behavior of sericite in microcrystalline graphite flotation. International Journal of Mineral Processing, 127, 1- 9.
 
20.
LI H.Q., OU L.M., FENG Q.M., CHANG Z.Y., 2015, Recovery mechanisms of sericite in microcrystalline graphite flotation. Physicochem. Probl. Miner. Process, 51(2), 386- 399.
 
21.
LI Y.J., SUN F.Y., ZHOU Y., ZENG L., 2015, The Improvement Effect of Dispersant in Fluorite Flotation: Determination by the Analysis of XRD and FESEM-EDX. Journal of Spectroscopy, 2015.
 
22.
LIN B.Y., 2011, Kyanite Andalusite Sillimanite. Beijing: Metallurgical Industry Press. (in Chinese).
 
23.
LU Y., LI H.Q., FENG Q.M., 2015, Entrainment behavior and control of sericite. Journal of Central South University (Science and Technology), 2015, 46(1), 20- 26. (in Chinese).
 
24.
LUO C., HE Y.Q., BU X.N., XIE W.N., WANG H.F., WANG S., 2015, An improved classic flotation kinetic model of narrow size slime. Journal of China University of Mining & Technology, (3), 477- 482. (in Chinese).
 
25.
MELO, F., LASKOWSKI, J. S., 2006, Fundamental properties of flotation frothers and their effect on flotation. Minerals Engineering, 19(6), 766- 773.
 
26.
NA Q., 1998, The Application of Acidic slag Sulphonate in Oxide Ore Flotation. METAL MINE, (5), 22- 24, (in Chinese).
 
27.
NEETHLING, S. J., CILLIERS, J. J., 2002, The entrainment of gangue into a flotation froth. International Journal of Mineral Processing, 64(2), 123- 134.
 
28.
OLIVEIRA, J. F., SARAIVA, S. M., PIMENTA, J. S., OLIVEIRA, A. P. A., 2001, Kinetics of pyrochlore flotation from Araxa mineral deposits. Minerals Engineering,14(1), 99- 105.
 
29.
Pita F A., 2015, True Flotation and Entrainment of Kaolinitic Ore in Batch Tests. Mineral Processing and Extractive Metallurgy Review, 36(4), 213- 222.
 
30.
POLAT, M., CHANDER, S., 2000, First-order flotation kinetics models and methods for estimation of the true distribution of flotation rate constants. International Journal of Mineral Processing,58(1), 145- 166.
 
31.
POLAT, M., POLAT, H., Chander, S., 2003, Physical and chemical interactions in coal flotation. International Journal of Mineral Processing, 72(1), 199- 213.
 
32.
SAVASSI, O. N., ALEXANDER, D. J., FRANZIDIS, J. P., MANLAPIG, E. V., 1998, An empirical model for entrainment in industrial flotation plants. Minerals Engineering, 11(3), 243- 256.
 
33.
SHI W.T., GAO H.M., ZHAO C.M., LIU G.J., REN Z.J., 2011, Experimental Research on Separation of Kyanite and Quartz by Flotation. Non-Metallic Mines, 34(6), 26- 28. (in Chinese).
 
34.
SUN C.Y., YIN W.Z., 2001, Flotation principle of silicate minerals. Beijing: Science Press. (in Chinese).
 
35.
SWEET, P. C., 1994, Silimanite group, kyanite and related minerals. Industrial Minerals and Rocks. Society for Mining, Metallurgy, and Exploration, Littleton, CO, 921- 928.
 
36.
TRUMIC, M. S., ANTONIJEVIC, M. M., 2016, Toner recovery from suspensions with fiber and comparative analysis of two kinetic models. Physicochem. Probl. Miner. Process, 52(1), 5- 17.
 
37.
UÇURUM, M., 2009, Influences of Jameson flotation operation variables on the kinetics and recovery of unburned carbon. Powder Technology,191(3), 240- 246.
 
38.
UÇURUM, M., BAYAT, O., 2007, Effects of operating variables on modified flotation parameters in the mineral separation. Separation and purification technology, 55(2), 173- 181.
 
39.
VINNETT, L., ALVAREZ-SILVA, M., JAQUES, A., HINOJOSA, F., YIANATOS, J., 2015, Batch flotation kinetics: Fractional calculus approach. Minerals Engineering, 77, 167- 171.
 
40.
WANG B., PENG Y., 2013, The behavior of mineral matter in fine coal flotation using saline water. Fuel, 109, 309- 315.
 
41.
WANG L., PENG Y., RUNGE, K., 2016, Entrainment in froth flotation: The degree of entrainment and its contributing factors. Powder Technology, 288, 202- 211.
 
42.
WANG L., PENG Y., RUNGE, K., Bradshaw, D., 2015, A review of entrainment: Mechanisms, contributing factors and modelling in flotation. Minerals Engineering, 70, 77- 91.
 
43.
WANG Q., 1992, Synergistic effect of petroleum-sodium sulfonate on rhodochrosite flotation. Mining and and Metallurgical Engineering, 12(4), 22- 25. (in Chinese).
 
44.
XU M., 1998, Modified flotation rate constant and selectivity index. Minerals Engineering, 11(3), 271- 278.
 
45.
YANG D.B., ZHANG Y.M., ZHAO Z.G., 2003, Study on Processing Flowsheet and Multipurpose Utilization of Yinshan Cyanite Mine. Conservation and Utilization of Mineral Resources, (3), 17- 19. (in Chinese).
 
46.
YEKELER, M., 1997, Effect of the hydrophobic fraction and particle size in the collectorless column flotation kinetics. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 121(1), 9- 13.
 
47.
ZHANG J.X., TAN Q.Q., ZHANG X.L., ZHAO J.W., NIU F.S., 2014, Study on flotation kinetics for kyanite, quartz and biotite. China Mining Magazine, 23(11), 115- 119. ( in Chinese).
 
48.
ZHANG J.S., QUE X.L., 2008, Mining agents. Beijing: Metallurgical Industry Press. (in Chinese).
 
49.
ZHANG W., MENG Q., DAI W.Y., 2013, Research on application of kyanite in plastic refractory. Chinese Journal of Geochemistry, 32(3), 326- 330.
 
50.
ZHAO G.X., ZHU B.Y., 2003, Principles of surfactant action. Beijing: China Light Industry Press. (in Chinese).
 
51.
ZHENG X., JOHNSON, N. W., FRANZIDIS, J. P., 2006, Modelling of entrainment in industrial flotation cells: water recovery and degree of entrainment. Minerals Engineering, 19(11), 1191- 1203.
 
52.
ZHU H.L., DENG H.B., CHEN C., 2015, Flotation separation of andalusite from quartz using sodium petroleum sulfonate as collector. Transactions of Nonferrous Metals Society of China, 25(4), 1279- 1285.
 
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