ORIGINAL ARTICLE
Nitrogen-Doped Carbon Dots from Pomegranate Peels as Sustainable Corrosion Inhibitors for Carbon Steel in Acidic Medium
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1
Department of Materials Science and Engineering, King Fahd University of Petroleum and Minerals
2
Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals
Submission date: 2025-07-11
Final revision date: 2025-10-28
Acceptance date: 2025-11-30
Publication date: 2025-12-31
Journal of Undergraduate Research International 2025;1(2):14-23
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ABSTRACT
Carbon dots from pomegranate-peel waste (PPCDs) and their N-doped counterparts (N-PPCDs) were hydrothermally synthesized and tested as corrosion inhibitors for carbon steel in 5 wt % HCl. Electrochemical (PDP, LPR, EIS) and weight-loss measurements, supported by surface imaging (SEM, AFM, and optical profilometry), showed inhibition efficiencies rising with concentration and peaking at 200 ppm. At this dose, PDP gave 70 % IE for PPCDs and 80 % for N-PPCDs; Rp increased from 52 Ω cm² (blank) to 151 Ω cm² (PPCDs) and 217 Ω cm² (N-PPCDs). N-PPCDs left the steel far smoother (Ra = 1.1 nm) than either PPCDs (2.4 nm) or the uninhibited surface (68 nm). Nitrogen doping enhanced adsorption and electron donation, making N-PPCDs a highly effective, sustainable corrosion inhibitor for acidic environments.