Bioleaching of indium and tin from used LCD panels
1
Silesian University of Technology, Department of Extractive Metallurgy and Environmental Protection, ul. Krasińskiego 8, Katowice, Poland
2
Czestochowa University of Technology, Department of Extraction and Recirculation of Metals,
ul. Armii Krajowej 21, Częstochowa, Poland
Corresponding author
Joanna Willner
Silesian University of Technology, Department of Extractive Metallurgy and Environmental Protection, ul. Krasińskiego 8, Katowice, Poland
Silesian University of Technology, Department of Extractive Metallurgy and Environmental Protection, ul. Krasińskiego 8, Katowice, Poland
Physicochem. Probl. Miner. Process. 2018;54(3):639-645
KEYWORDS
TOPICS
ABSTRACT
The demand for indium is increasing every year. This metal is mainly used as indium tin oxide (ITO) in the production of transparent conductive coatings for liquid crystal displays (LCD). This paper focuses on biohydrometallurgical methods used for the recovery of indium and tin from LCD sourced from spent mobile phones. Bioleaching experiments were carried out in two different leaching media: 9K medium and H2SO4 solution, using mixed, adapted bacteria Acidothiobacillus ferrooxidans and Acidothiobacillus thiooxidans. The main aim of this study was to evaluate the potential and efficiency of indium and tin extraction in the presence of acidophilic microorganisms. Within 35 days, using 9K medium, 55.6% of indium was bioleached, whereas the chemical leaching resulted in a value of 3.4%. Leaching efficiency of tin was 90.2% on the 14th day of the experiment for the biological system (9K) and 93.4% on 21st day of control leaching.
REFERENCES (21)
1.
ALFANTAZI, A.M., MOSKALYK, R.R., 2003. Processing of indium: a review, Miner. Eng., 16, 687-694.
2.
BRANDL, H., BOSSHARD, R., WEGMANN, M., 2001. Computer-munching microbes: metal leaching from electronic scrap by bacteria and fungi, Hydrometallurgy, 59, 319–326.
3.
CHEN, P., YAN, L., WANG, Q., LI, H., 2013. Arsenic precipitation in the bioleaching of realgar using Acidithiobacillus ferrooxidans, J. Appl. Chem., 1-5.
4.
EISEN, N., SCHLOMANN, M., SCHOPF, S., 2016. Bioleaching of indium-bearing sphalerite under underground mining temperatures, Proceedings IMWA, Mining meets water – conflict and solutions, Freiberg, Germany, 1058-1059.
5.
GIBSON, C., HAYES, T., 2011. Indium and gallium overview, Edison Investment Research, 1-10.
6.
ILYAS, S., ANWAR, M.A., NIAZI, S.B., GHAURI, M.A., 2007. Bioleaching of metals from electronic scrap by moderately thermophilic acidophilic bacteria, Hydrometallurgy, 88, 180-188.
7.
JENSEN, A.B., WEBB, C., 1995. Ferrous sulphate oxidation using Thiobacillus ferrooxidans: a review, Process. Biochem., 30, 225–236.
8.
LUPTAKOVA, A., MACINGOVA, E., HARBULAKOVA, V., 2009. Positive and negative aspects of sulphate-reducing bacteria in environment and industry, Nova Biotechnol., 9-2, 147-154.
9.
MARTIN, M., JANNECK, E., KERMER, R., PATZIG, A., REICHEL, S., 2015. Recovery of indium from sphalerite ore and flotation tailings by bioleaching and subsequent precipitation processes, Miner. Eng., 75, 94–99.
10.
MOLAEI, S., YAGHMAEI, S., GHOBADI, Z., 2011. A study of Acidithiobacillus ferrooxidans DSMZ 583 adaptation to heavy metals, Iranian J. Biotechnol., 9, 2, 133-144.
11.
PACHOLEWSKI, A., PACHOLEWSKA, M., 2001. Naturalne zdolności do utleniania jonu Fe2+ oraz S2O3 - przez bakterie żelazowe ze źródła wody mineralnej Łomniczanka, [in:] Współczesne Problemy Hydrogeologii, t. X Ogólnopolska Konferencja Naukowa, Krzyżowa, 389-396.
12.
PONGRACZ, E., 2014. Critical Minerals: recycling vs. dissipative losses – the case of indium, Proceedings SUM, Bergamo, Italy, CISA Publisher.
13.
SATERNUS, M., WILLNER, J., FORNALCZYK, A., LISIŃSKA, M., 2017. Rare earth metals. Receiving and recovery from waste materials, Przem. Chem., 96, 1000-1004.
14.
SILVEIRA, A.V.M., FUCHS, M.S., PINHEIRO, D.K., TANABE, E.H., BERTUOL, D.A., 2015. Recovery of indium from LCD screens of discarded cell phones, Waste Manage., 45, 334-342.
15.
SMITH, P.J., (Ed.), 1998. Chemistry of Tin, Springer Science + Business Media, Glasgow, Chap. 3.
16.
WANG, H.Y., 2009. A study of the effects of LCD glass sand on the properties of concrete, Waste Manage., 29, 1, 335-341.
17.
WILLNER, J., FORNALCZYK, A. 2012. Electronic scraps as a source of precious metals, Przem. Chem., 91, 517-522.
18.
WILLNER, J., KADUKOVA, J., FORNALCZYK, A., SATERNUS, M., 2015. Biohydrometallurgical methods for metals recovery from waste materials, Metallurgy, 54, 1, 255-259.
19.
WILLNER, J., 2013. Influence of physical and chemical factors on biological leaching process of copper from printed circuit boards, Metallurgy, 52, 2, 189-192.
20.
YANG, J., 2012. Recovery of indium from end-of-life Liquid Crystal Diplays, BSc Thesis, Chalmers University of Technology, Gothenburg, Sweden.
21.
ZHANG, K., WU, Y., WANG, W., LI, B., ZHANG, Y., ZUO, T., 2015. Recycling indium from waste LCDs: A review, Resour. Conserv. Recycl., 104, 276–290.
Share
RELATED ARTICLE
| eISSN: | 2084-4735 |
| ISSN: | 1643-1049 |
We process personal data collected when visiting the website. The function of obtaining information about users and their behavior is carried out by voluntarily entered information in forms and saving cookies in end devices. Data, including cookies, are used to provide services, improve the user experience and to analyze the traffic in accordance with the Privacy policy. Data are also collected and processed by Google Analytics tool (more).
You can change cookies settings in your browser. Restricted use of cookies in the browser configuration may affect some functionalities of the website.
You can change cookies settings in your browser. Restricted use of cookies in the browser configuration may affect some functionalities of the website.
