Contribution on fluid inclusion abundance to activation of quartz flotation
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Wuhan University of Technology
Hubei Key Laboratory of Mineral Resources Processing & Environment
Bengbu Design & Research Institute for Glass Industry
Lingyan Zhang   

Wuhan University of Technology
Physicochem. Probl. Miner. Process. 2018;54(3):981–991
In this study, comparative experiments were conducted on the recovery of quartz using flotation with different fluid inclusion abundances. A large number of fluid inclusions with various sizes have been found in natural quartz. Micrographs, inductively coupled plasma, electron probe microanalysis, homogenization temperature, Raman spectra, zeta potentials, X-ray photoelectron spectroscopy, scanning electron microscope, and energy dispersive spectrometer were used to characterize the fluid inclusions and quartz, as well as the adsorption tests and single mineral flotation experiments to investigate its floatability. The results demonstrated that it was more likely for quartz with higher fluid inclusion abundance to connect with Fe3+ sufficiently to achieve a high level of flotation recovery, due to the powerful collecting ability by sodium dodecyl sulphonate to Fe3+. Furthermore, the mechanism indicated that the adsorption between quartz and Fe3+ was a process of chemisorption.
ALLEN G. C., 2004. X-ray photoelectron study of oxygen bonding in crystalline C-S-H phases. Phys. Chem. Minerals, 31, 337–346.
BODNAR R. J., 1993. Revised equation and table for determining the freezing point depression of H2O-NaCl solutions. Geochim. Cosmochim. Acta, 57, 683–684.
BURKE E A. J., 2001. Raman microspectrometry of fluid inclusions. Lithos, 55, 139-158.
CHANDRA A.P., GERSON A.R., 2009. A review of the fundamental studies of the copperactivation mechanisms for selective flotation of the sulfide minerals, sphaleriteand pyrite. Advanced Colloid Interface Science, 145, 97–110.
DU F. H., LI J. S., LI X. X., ZHANG Z. Z.,2011. Improvement of iron removal from silica sand using ultrasound-assisted oxalic acid. Ultrason. Sonochem.,18,389-393.
DUBESSY J., BOIRON M., MOISSETTE A., MONNIN C., SRETENSKAYA N.,1992, Determinations of water , hydrates and pH in fluid inclusions by micro-Raman spectrometry. Eur. J. Mineral, 4, 885–894.
FAN C. H., MA, H. R., HUA, L., WANG, J. H., WANG H. J., 2012, FTIR and XPS Analysis of Characteristics of Synthesized Zeolite and Removal Mechanisms for Cr (III). Spectroscopy and Spectral Analysis, 32, 324–329. (in Chinese).
GOLDSTEIN R. H., 2001. Fluid inclusions in sedimentary and diagenetic systems. Lithos, 55, 159–193.
HOU Q., JING L., Yin R., CHEN L., LU L., JI F., 2012. Study on Gas-Liquid Inclusions in Quartz Sand under Microwave Field. Adv. Mater. Res, 689–693.
HUANG P., FUERSTENAU D. W., 2001. The effect of the adsorption of lead and cadmium ions on the interfacial behavior of quartz and talc. Colloids Surfaces A Physicochem. Eng. Asp, 177, 147–156.
KOH P. T. L., HAO F. P., SMITH L. K., CHAU T. T., BRUCKARD W. J., 2009. The effect of particle shape and hydrophobicity in flotation. Int. J. Miner. Proc., 93, 128–134.
KRASOWSKA M., MALYSA K., 2007. Kinetics of bubble collision and attachment to hydrophobic solids: effect of surface roughness. Int. J. Miner. Proc., 81, 205–216.
LARSEN E., KLEIV R. A., 2015. Towards a new process for the flotation of quartz. Miner. Eng., 83, 13–18.
LI J., LI X., DU F., 2010. Further Purification of Industrial Quartz by Much Milder Conditions and a Harmless Method. Environ. Sci. Technol., 44, 7673–7677.
LIU J., WEN, S., DENG J., CAO, Q., MILLER J. D., WANG X., 2013. Contribution of fluid inclusions to variations in solution composition for sphalerite/quartz samples from the Yunnan Province, PRC. Colloids Surfaces A Physicochem. Eng. Asp., 436, 287–293.
LU H. Z. et al., 2004. Fluid inclusions. Beijing , China :Science Press.
LUCE M., TECCE F., CASAGLI A., 2012. Raman spectroscopy for fluid inclusion analysis. J. Geochemical Explor., 112, 1–20.
LUO B., ZHU Y., SUN C., LI Y., HAN Y., 2015. Flotation and adsorption of a new collector α-Bromodecanoic acid on quartz surface. Miner. Eng, 77, 86–92.
MOWLA D., KARIMI G., OSTADNEZHAD K., 2008. Removal of hematite from silica sand ore by reverse flotation technique. Sep. Purif. Technol., 58,419-423.
NIE Y. M., LU X. L., NIU F. S., 2013. Purification Experiment Research of Quartz Sand. Appl. Mech. Mater., 389, 346-348.
PARIS-NORD U., MOLTKULAIRE P., PARWSUD U., MOIPCULAIRE L. D. S.,1989. Density effect on the Raman fermi resonance in the fluid phases of CO2. Chem. Phys. Lett., 160, 250–256.
PLATIAS S., VATALIS K. I., CHARALABIDIS G., 2013. Innovative processing techniques for the production of a critical raw material the high purity quartz. Procedia Econ. Financ, 5, 597–604.
SAHOO H., RATH S. S., DAS B., 2014. Use of the ionic liquid-tricaprylmethyl ammonium salicylate (TOMAS) as a flotation collector of quartz. Sep. Purif. Technol., 136, 66-73.
SANTOS M. F. M., FUJIWARA E., SCHENKEL E. A., ENZWEILER J., SUZUKI C. K., 2015. Processing of quartz lumps rejected by silicon industry to obtain a raw material for silica glass. Int. J. Miner. Process, 135, 65–70.
TUNCUK A., AKCIL A., 2016. Iron removal in production of purified quartz by hydrometallurgical process. Int. J. Miner. Process, 153, 44–50.
VAN DEN KERKHOF A. M., HEIN U.F., 2001. Fluid inclusion petrography. Lithos, 55, 27-47.
VATALIS K. I., CHARALAMBIDES G., BENETIS N. P., 2015. Market of high purity quartz innovative applications. Procedia Econ. Financ, 24, 734–742.
VAZIRI HASSAS B., CALISKAN H., GUVEN O., KARAKAS F., CINAR M., CELIK M. S., 2016. Effect of roughness and shape factor on flotation characteristics of glass beads. Colloids Surfaces A Physicochem. Eng. Asp., 492, 88–99.
VEGLIO F., PASSARIELLO B., ABBRUZZESE C., 1999. Iron Removal Process for High-Purity Silica Sands Production by Oxalic Acid Leaching. Ind. Eng. Chem. Res., 38, 4443–4448.
WANG Y. H., REN J. W., 2005. The flotation of quartz from iron minerals with a combined quaternary ammonium salt. Int. J. Miner. Proc., 77, 116–122.
XIA W., 2017. Role of particle shape in the floatability of mineral particle: An overview of recent advances. Powder Technol., 317, 104–116.
XU J. G., 1991. Theory and practice of fluid inclusion micro-thermometry with infrared microscope within opaque minerals. Geol. Sci. Technol. Inf., 10, 91–95. (in Chinese).
ZHAI Q., 2010. Catalytic kinetic spectrophotometric determination of sodium dodecyl sulphonate. Instrum. Sci. Technol., 38, 135–142.
ZHANG Z. Z., LI J. S., LI X. X., HUANG H. Q., ZHOU L. F., XIONG T. T., 2012. High efficiency iron removal from quartz sand using phosphoric acid. Int. J. Miner. Proc., 114-117, 30–34.